Determination of Soil Contamination by Some Heavy Metals Using Chemical Techniques and a Spectroradiometer at Two Sites in Erbil Governorate, Iraq

Volume 17, Issue 2
Spring 2026
Page 78-85

Document Type : Research Paper

Authors

1 Salahaddin University (College of Agriculture Engineering Science) -Erbil

2 Department of Soil and Water, College of Agriculture Engineering Sciences, Salahaddin University, Erbil, Kurdistan Region, IRAQ

Abstract
Polluted soil samples were randomly collected in August 2024 around two sources of pollution (Gas Station and Steel Factory), which are located in the south and west of Erbil city. Each sample was about 100 meters away from the source of pollution, and the control samples were about 1 km away from the source, and the soil samples were taken from 0–30 cm depth in the study area. Then, some chemical and physical properties and the spectral reflectance of the soil samples were determined by spectroradiometer (ASD-Field Spectro), in order to know its relation with heavy metal concentrations and other soil properties. The study showed that the Cd concentration in Steel Factory > Gas Station, the Pb and Ni concentration in Gas Station > Steel Factory, on the other hand the highest value of spectral reflectance was at the Gas Station sample (G11), and the lowest reflectance value was at the Steel Factory sample (S6). The results indicate that the concentrations of heavy metals (Cd, Pd and Ni) in soils from contaminated sites were significantly higher than those in the control samples, which the control sites remain largely unaffected. The results of this study emphasize the critical necessity for regular and systematic monitoring of fuel-related activities and industrial operations within the study region in order to prevent additional soil degradation. The excessive buildup of heavy metals in the soil may be avoided in large part by enacting stricter and more thorough environmental rules and implementing well-thought-out remediation plans. In addition to preserving and enhancing soil quality, such actions would ensure the long-term viability of regional ecosystems and enhance agricultural output for upcoming generations, improving living standards and lowering possible health hazards.

Keywords

Subjects
[1].   Jacob, J.M., Karthik, C., Saratale, R.G., Kumar, S.S., Prabakar, D., Kadirvelu, K. and Pugazhendhi, A., 2018. Biological Approaches to Tackle Heavy Metal Pollution: A Survey of Literature. Journal of Environmental Management, 217, Pp.56-70.
[2].   Hussain, G. A., Umer, M. I., & Ahmed, M. R. 2023. A Study on The Contamination of Khabur River with Heavy Metals Due to Spatial and Seasonal Discharged Wastewater in the Iraqi Kurdistan Region: Heavy Metals. Science Journal of University of Zakho, 11(2), 298-305.
[3].   Bărbulescu, A. and Hosen, K., 2025. Cement Industry Pollution and its Impact on the Environment and Population Health: A Review. Toxics, 13(7), P.587.
[4].   Ahmed, I.T. and Esmail, A.O., 2013. Relationship Between Soil Physico-Chemical Properties and the Spectral Reflectance's of Some Soil Sites from Arbil Governorate.
[5].   Osioma, E. and Iniaghe, P.O., 2022. Concentration and Bioaccumulation of Toxic Metals and
      Polycyclic Aromatic Hydrocarbons in Soil and Lumbricus Terrestris in Kolo Creek, Niger
      Delta, Nigeria. Am. J. Agric. Sci. Eng. Technol, 6(2), Pp.1-9.
[6].   www.daringrroup.com .2023
[7].   Salih, Z.R., Othman, B.A. and Aweez, S.J., 2024. Assessment of Heavy Metals in Rainfall as an Indicator of Air Pollution from Erbil Steel Factory in Iraq. Environmental Monitoring and Assessment, 196(3), P.319.
[8].   Klute, A. and Page, A.L., 1986. Methods of Soil Analysis. American Society of Agronomy. Agronomy Monograph, 9.
[9].   Munsell Soil Color Charts, 1954 Edition, Published by the Munsell Color Company.
[10].  Jackson, M.L., 1958. Soil Chemical Analysis Practice. Hall. Inc. Eagle Wood Chaff, New York.
[11].  Hesse, P., 1971. R” A Textbook of Soil Chemical Analysis” William Clowes and Sons Limited.
[12].  Rowell, D. L., 1996. Soil Science: Methods and Application. University of Reading. Uk.
[13].  Hseu, Z.Y., Chen, Z.S., Tsai, C.C., Tsui, C.C., Cheng, S.F., Liu, C.L. and Lin, H.T., 2002. Digestion Methods for Total Heavy Metals in Sediments and Soils. Water, Air, and Soil Pollution, 141(1), Pp.189-205.
[14].  Radpour, R., Delaney, J.K. and Kakoulli, I., 2022. Acquisition of High Spectral Resolution Diffuse Reflectance Image Cubes (350–2500 Nm) from Archaeological Wall Paintings and other
[15].  Sun, Z., Zhang, W., Sun, H., Wang, J., Chen, Q. and Yuan, C., 2023. Organic Matter Addition Promotes Cd Immobilization in Alkaline Paddy Soils. Carbon Research, 2(1), P.36.
[16].  Zgorelec, Ž., Zubčić, L., Žužul, S., Kljaković-Gašpić, Z., Trkmić, M., Galić, M., Hrelja, I., Špehar Ćosić, A., Perčin, A. and Bilandžija, N., 2025. High Cadmium and Mercury Soil Contamination Outweighs the Effect of Soil Amendments When Growing Miscanthus X Giganteus. Applied Sciences, 15(16), P.9075.
[17].  Yasin, S.A. and Salih, Z.R., 2025. Assessing Air Quality Impacts of Gas Stations Through Heavy Metal Analysis in Dust and Employees’ Scalp Hair in Erbil City. Environmental Monitoring and Assessment, 197(4), P.410.
[18].  He, J., Zhang, Q. and Achal, V., 2020. Heavy Metals Immobilization in Soil with Plant-Growth-Promoting Rhizobacteria and Microbial Carbonate Precipitation in Support of Radish Growth. Microbiology and Biotechnology Letters, 48(2), Pp.223-229.
[19].  George, S.E. and Wan, Y., 2023. Microbial Functionalities and Immobilization of Environmental Lead: Biogeochemical and Molecular Mechanisms and Implications for Bioremediation. Journal of Hazardous Materials, 457, P.131738.
[20].  Zhou, H., Ouyang, T., Guo, Y., Peng, S., He, C. and Zhu, Z., 2022. Assessment of Soil Heavy Metal Pollution and its Ecological Risk for City Parks, Vicinity of a Landfill, and an Industrial Area Within Guangzhou, South China. Applied Sciences, 12(18), P.9345.
[21].  Hou, D., Jia, X., Wang, L., Mcgrath, S.P., Zhu, Y.G., Hu, Q., Zhao, F.J., Bank, M.S., O’connor, D. and Nriagu, J., 2025. Global Soil Pollution by Toxic Metals Threatens Agriculture and Human Health. Science, 388(6744), Pp.316-321.
[22].  Zhang, Y., Wang, Y., & Liu, J., 2021. "Environmental Pollution and Health Risks from Steel Industry in China: A Systematic Review." Environmental Pollution, 276, 116625.
[23].  Alloway, B.J., 2013. Heavy Metals in Soils: Trace Metals and Metalloids in Soils and Their Bioavailability. 3rd Ed. Dordrecht: Springer, Pp. 135–138.
[24].  Zolotova, E., Ivanova, N. and Ayan, S., 2025. Monitoring of Air Pollution from the Iron and Steel Industry: a Global Bibliometric Review. Atmosphere, 16(8), P.992.
[25].  Kabata-Pendias, A., 2011. Trace Elements in Soils and Plants. 4th Ed. Boca Raton, Fl: Crc Press, Pp. 77–80.
[26].  Yu, J.A., Chen, Z., Gao, W., He, S., Xiao, D., Fan, W., Huo, M. and Nugroho, W.A., 2025. Global Trends and Prospects in Research on Heavy Metal Pollution at Contaminated Sites. Journal of Environmental Management, 383, P.125402.
[27].  Hua, J., Zhao, Y., Zhang, Y., Zhu, Y., Liu, C., Wang, F., Xu, X. and Yu, Q., 2025. Environmental and Health Risk Assessment of Fugitive Dust from Magnesium Slag Yards. Toxics, 13(4), P.307.
[28].  Kurniati, E.O., Pederson, F. and Kim, H.J., 2023. Application of Steel Slags, Ferronickel Slags, and Copper Mining Waste as Construction Materials: A Review. Resources, Conservation and Recycling, 198, P.107175.
[29].  Alloway, B.J., 2013. Sources of Heavy Metals and Metalloids in Soils. in Heavy Metals in Soils: Trace Metals and Metalloids in Soils and their Bioavailability (Pp. 11-50). Dordrecht: Springer Netherlands.
[30].  Ma, W., Zhou, H., Hu, H., Zhuo, Z., Zhu, K. and Zhang, G., 2025. Estimation of soil free Iron content using spectral reflectance and machine learning algorithms. Scientific Reports, 15(1), p.23928.
[31].  Mirza, D.K. and Ahmed, I.T., 2023. Impact of Crude Oil discharge from Oil Refineries near Gwer Road of Erbil City on Soil Physico-chemical Properties and Metal Emancipations. ZANCO Journal of Pure and Applied Sciences, 35(1), pp.78-87.
[32].  Kabata-Pendias, A. (2011). Trace Elements in Soils and Plants (4th ed.). CRC Press, Taylor & Francis Group.
[33].  Nabulo, G., Oryem-Origa, H. & Diamond, M., 2006. Assessment of lead, cadmium and zinc contamination of roadside soils in Kampala, Uganda. Science of the Total Environment, 359(1–3), pp.45–61. This study shows total Pb decreased with distance from the road and reached background soil concentrations at ~30 m.